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Temperature waves in chemical reaction-diffusion-heat conduction systems with two ends respectively subject to Dirichlet and no-flux conditions

Temperature waves in chemical reaction-diffusion-heat conduction systems with two ends respectively subject to Dirichlet and no-flux conditions

作     者:Yu Min Han Zhi Li Jiu Li Luo 

作者机构:Institute of Chemical Physics College of Chemistry Sichuan University Chengdu 610064 China 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2007年第18卷第11期

页      面:1427-1430页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

基  金:Ministry of Education of the People's Republic of China  MOE  (20050610012) 

主  题:Temperature waves Lindemann model Chemical reaction-diffusion-heat conduction 

摘      要:Taking the Lindemann model as a sample system in which there exist chemical reactions, diffusion and heat conduction, we found the theoretical framework of linear stability analysis for a unidimensional nonhomogeneous two-variable system with one end subject to Dirichlet conditions, while the other end no-flux conditions. Furthermore, the conditions for the emergence of temperature waves are found out by the linear stability analysis and verified by a diagram for successive steps of evolution of spatial profile of temperature during a period that is plotted by numerical simulations on a computer. Without doubt, these results are in favor of the heat balance in chemical reactor designs.

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