Production of Camphene by Isomerization Reaction on Sulfated ZrO2

作     者：Nora Alejandra Comelli,Omar Masini,Alfredo Lzaro Carrascull,Esther Natalia Ponzi,Marta Isabel Ponzi 

作者机构：INTEQUI(CONICET-UNSL) Facultad de Ingenieriay Ciencias Economico Sociales 25 de Mayo 384 V.Mercedes (SL) Argentina INTEQUI(CONICET-UNSL) Facultad de Ingenieriay Ciencias Economico Sociales 25 de Mayo 384 V.Mercedes (SL) Argentina INTEQUI(CONICET-UNSL) Facultad de Ingenieriay Ciencias Economico Sociales 25 de Mayo 384 V.Mercedes (SL) Argentina INTEQUI(CONICET-UNSL) Facultad de Ingenieriay Ciencias Economico Sociales 25 de Mayo 384 V.Mercedes (SL) Argentina CINDECA(CONICET-UNLP)Calle 47 N°257 1900 La Plata Argentina 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报(英文))

年 卷 期：2000年第1期

页      面：68-71页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：camphene kinetics a-pinene zirconium oxide superacid catalyst 

摘      要：Abstract The kinetics of camphene production in liquid phase from α-pinene was experimentally determinedin an isothermal batch *** this end,a sulfated ZrO2catalyst was used and the reaction studied in thetemperature range of *** analyzing the experimental data,second reaction order for α-pinene wasfound.A kinetic model is presented which includes term for the catalyst load *** specific rate constant at393K was 2.19×10-3mol.L-1,min-1,the activation energy being *** Vaues are within the rangeof literature results.