Synthesis,Crystal Structure and Thermal Stability of a One-dimensional Chain Cobalt Coordination Polymer [Co(4,4'-bipy)(2,4,6-TMBA)_2(CH_3CH_2OH)_2]_n

作     者：LI Wei LI Chang-Hong YANG Ying-Qun CHEN Zhi-Min KUANG Dai-Zhi ZHANG Chun-Hua KANG Yun-Fei 

作者机构：Department of Chemistry and Materials Science Hengyang Normal University Hengyang 421008 China Department of Chemical Engineering Hunan Institute of Technology Hengyang 421008 China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2006年第25卷第7期

页      面：878-882页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：Project supported by the Natural Science Foundation of Hunan Province (No. 05JJ30016)  Foundation of Education Committee of Hunan Province (05C001)  Foundation of Hengyang Sci. & Tech. Bureau (2005Cg10-23) and Fund for Distinguished Young Cadreman of Hengyang Normal University(2006) 

主　　题：cobalt(Ⅱ) complex crystal structure thermal stability analysis 

摘      要：A one-dimensional chain cobalt（Ⅱ） coordination polymer with 2,4,6-trimethyl- benzoic acid, 4,4′-bipyridine and cobalt perchlorate anhydrous has been synthesized and characterized in the mixture solvent of water and alcohol. Crystal data for this complex： monoclinic, space group C2/c, a = 2.3805（8）, b = 1.1464（4）, c = 1.5807（5） nm, y = 128.435（4）°, V= 3.3791（18） nm^3, Dc = 1.246 g/cm^3, Z = 4, F（000） = 1340, final GooF = 1.009, R = 0.0504 and wR = 0.1287. Structural analysis shows that the cobalt ion is coordinated with two nitrogen atoms of one 4,4′- bipyridine molecule and four oxygen atoms from two 2,4,6-trimethylbenzoic acid molecules and two alcohol molecules, giving a distorted octahedral coordination geometry. The result of TG analysis indicates that the title complex is stable till 200 ℃.