Perchlorates as Powerful Catalysts in Many Important Organic Transformations

作     者：G. Bartoli L. Sambri M. Locatelli 

作者机构：Department of Organic Chemistry "A. Mangini" Bologna University v.le Risorgimento 4 Bologna 40136 ItalyDepartment of Organic Chemistry "A. Mangini" Bologna University v.le Risorgimento 4 Bologna 40136 ItalyDepartment of Organic Chemistry "A. Mangini" Bologna University v.le Risorgimento 4 Bologna 40136 Italy 

出 版 物：《复旦学报（自然科学版）》 (Journal of Fudan University：Natural Science)

年 卷 期：2005年第44卷第5期

页      面：650-651页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：theUniversityofBologna intheframeworkof"ProgettodiFinanziamentoPluriennale AteneodiBologna" andbyNationalprojectFIRB"Progettazione preparazioneevalutazionebiologicaefarmacologicadinuovemolecoleorganichequalipotenzialifarmaci" 

主　　题：全氯乙烯 催化剂 有机变化 合成方法 金属 

摘      要：For long times, metallic perchlorates have been considered dangerous compounds[1] in that they function as explosives and as incontrollable ***, the fear of the great hazard connected with their manufacture and uses had prevented an extensive use both in research laboratories and in industrial processes[2].However, recently it has been cleared that this bad reputation is due to the mistaken association of metallic perchlorates with the oxidizing potential of perchloric acid and the pyrotechnic performances of NH4ClO4.