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Raman Scattering Modification Induced by Structural Change in Alumina Polymorphs

Raman Scattering Modification Induced by Structural Change in Alumina Polymorphs

作     者:张建 李海涛 郭俊宏 胡芳仁 

作者机构:School of Physics Beijing Institute of Technology Beijing 100081 Department of Physics Chengde Teacher's College for Nationalities Chengde 067000 School of Optoelectronic Engineering and Griienberg Research Centre Nanjing University of Posts and Telecommunications Nanjing 210023 

出 版 物:《Chinese Physics Letters》 (中国物理快报(英文版))

年 卷 期:2015年第32卷第12期

页      面:105-108页

核心收录:

学科分类:081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 0703[理学-化学] 

基  金:Supported by the National Natural Science Foundation of China under Grant Nos 61505085 and 61574080 

主  题:Raman Scattering Modification 

摘      要:The calculated Raman spectra disclose that alumina polymorphs of nordstrandite, gibbsite, diaspore, boehmite, bayerite and α-Al2O3 display different phonon behaviors, which can be attributed to their internal crystal structure changes. The strongest Raman peaks of nordstrandite, gibbsite, diaspore, boehmite, bayerite and α-Al2O3 are located at 214.2cm-1, 3314.4cm-1, 2298.6cm-1, 747.7cm-1, 3484.6cm-1 and 529.2cm-1, respectively. The characterizations in Raman spectra of those polymorphs are obviously different, which can be used in fingerprints to identify the alumina polymorphs structure.

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