Kinetics of 2-Methylbutene-2 Epoxidation with 2-Methylbutane Hydroperoxide

作     者：Valentin N. Sapunov Aleksandr A. Petukhov Liubov A. Petukhova 

作者机构：University of Chemical Technology Moscow Russia National Research Technological University (KNRTU) Kazan Russia 

出 版 物：《Journal of Chemistry and Chemical Engineering》 (化学与化工（英文版）)

年 卷 期：2013年第7卷第4期

页      面：356-363页

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 09[农学] 0903[农学-农业资源与环境] 070303[理学-有机化学] 0703[理学-化学] 0713[理学-生态学] 

主　　题：Kinetic 2-methylbutene-2 epoxidation 2-methylbutane hydroperoxide molybdenum catalyst mathematical description. 

摘      要：The kinetics of epoxidation of methylbutene with structurally identical methylbutane hydroperoxide was studied in the presence of a molybdenum catalyst. The analysis of the rate curves suggested the most probable scheme of the process. The revealed features of the process and its mathematical description make it possible to more competently design a reactor unit for the commercial production of isoprene according to the developed scheme. The main kinetic constants were calculated.