AMINO-TRIS-(METHYLENEPHOSPHONIC ACID)LAYERS ADSORPTION ON AA6061 ALUMINUM ALLOY

作     者：S.H. Wang C.S. Liu F.J. Shan G.C. Qi 

作者机构：Key Laboratory for Anisotropy and Texture of Materials Ministry of Education Northeastern University Shenyang 110004 China Material＆ Chemical Engineering College Liaoning University of Technology Jinzhou 121001 China 

出 版 物：《Acta Metallurgica Sinica(English Letters)》 (金属学报（英文版）)

年 卷 期：2008年第21卷第5期

页      面：355-361页

核心收录：

学科分类：080503[工学-材料加工工程] 08[工学] 0805[工学-材料科学与工程（可授工学、理学学位）] 

基　　金：the Science and Technology Plan Project of LiaoningProvince  China (No.2006221011) 

主　　题：Amino-tri-(methylenephosphonic acid) layer Organophosphonate Aluminum alloy Corrosion resistance 

摘      要：The amino-tri-（methylenephosphonic acid） layers were adsorbed on the surface of AA6061 aluminum alloy for improving the lacquer adhesion and corrosion inhibition as a substitute for chromate coatings. The surface structure and characteristic of the amino-tri-（methylenephosphonic acid） layers on AA6061 aluminum alloy were investigated by means of XPS and ATR-FTIR analysis. The analyzed results showed that the amino-tri-（methylenephosphonic acid） adsorption layers adsorb on the surface of aluminium alloy via acid-base interaction in a bi-dentate conformation. After the amino-tri-（methylenephosphonic acid） layers were coated with epoxy resin, the layers showed good adhesive strength and favorable corrosion resistance in contrast to chromate coatings.