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Adsorption of Methylene Blue on magnesium silicate: Kinetics, equilibria and comparison with other adsorbents

Adsorption of Methylene Blue on magnesium silicate: Kinetics, equilibria and comparison with other adsorbents

作     者:Franco Ferrero 

作者机构:Department of Materials Science and Chemical Engineering Polytechnic of Torino Corso Duca degli Abruzzi 24 I10129 Torino Italy 

出 版 物:《Journal of Environmental Sciences》 (环境科学学报(英文版))

年 卷 期:2010年第22卷第3期

页      面:467-473页

核心收录:

学科分类:083001[工学-环境科学] 0830[工学-环境科学与工程(可授工学、理学、农学学位)] 08[工学] 

主  题:dye adsorption magnesium silicate Florisil adsorption kinetics adsorption isotherms 

摘      要:Batch adsorption from aqueous solutions in a slightly basic medium of Methylene Blue, up to 2500 mg/L, onto synthetic magnesium silicate (Florisil) of three particle size ranges (mean diameters of 112, 200 and 425 μm) was compared to the corresponding adsorption onto activated carbon and Amberlite XAD-2. The best fit of the kinetic results was achieved by a pseudo second-order equation. The equilibrium data were found to be well represented by the Langmuir isotherm equation. Amberlite XAD-2, an unspecific adsorbent capable of adsorbing exclusively through a surface effect, exhibited a poor dye uptake, confirming that the adsorption mechanism on Florisil was due to electrostatic attraction and ion exchange. Moreover, the comparison between Florisil and the other adsorbents was performed on the basis of the evaluation of the surface area and pore volume occupied by the adsorbed dye.

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