Regularities of formation of binary intermetallic compounds between transition and non-transition elements
Regularities of formation of binary intermetallic compounds between transition and non-transition elements作者机构:Shanghai Jiao Tong Univ Inst Image Proc & Pattern Recognit Shanghai 200030 Peoples R China
出 版 物:《Chinese Science Bulletin》 (Chin. Sci. Bull.)
年 卷 期:2001年第46卷第21期
页 面:1845-1848页
核心收录:
学科分类:07[理学] 070205[理学-凝聚态物理] 0702[理学-物理学]
主 题:transition metal non-transition metal intermetallic compound formation criterion.
摘 要:A four-parameter model based on the extended Miedema’s cellular model of alloy phases and pattern recognition methods has been used to study the regularities of the formation of binary intermetallic compounds between tran-sition element and non-transition element. The formation criterion can be expressed as some inequities of electronega-tivity , the valence electron density in Wagner-Seitz cell nws1/3, Pauling’s metallic radius R and the number of valence electrons in atom Z or their functions. According to these empirical criterions, the unknown binary alloy system can be predicted, the predicted result is better than that of Miedema’s two-parameter model.