Influence of Different Surfactants on Morphology of Single Crystal Ce2O（CO3）2·H2O and Formation Mechanism

作     者：Yan Mei Ye-bin Han Zuo-ren Nie Yan Mei;Ye-bin Han;Zuo-ren Nie

作者机构：College of Materials Science and Engineering Beijing University of Technology Beijing 100022 China 

出 版 物：《Chinese Journal of Chemical Physics》 (化学物理学报（英文）)

年 卷 期：2006年第19卷第3期

页      面：269-272页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 070304[理学-物理化学(含∶化学物理)] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

主　　题：Surfactant Homogeneous precipitation Single crystal Morphology Mechanism 

摘      要：Three kinds of ultra-fine Ce2O（CO3）2·H2O powders with different morphologies were prepared by adding CTAB, PEG19000 and OP-10 to a solution of Ce2O（NO3）3·6H2O and urea according to the principle and the characteristics of the homogeneous precipitation method. The products were characterized by TEM and XRD. The results showed that the precursor was a single crystal, and that different surfactants had different influences on the morphology of the products. The cationic surfactant CTAB had little effect on crystal morphology merely reducing its size. Nonionic surfactants PEG19000 and OP-10 are both able to change the crystal morphology to a much greater extent. Adding PEG19000 produces an array of rod-like particles with ordered formation and uniform dimension. Meanwhile, in the system of OP-10, a sort of flower-like pattern with a dispersed center can be prepared. The formations of ultra-fine Ce2O（CO3）2·H2O powders with different morphologies occured because of the mechanism of formation and grain growth.