Synthesis and Crystal Structure of Zn(II) Complex with Tridentate Ligand N-(2-Hydroxy-1-naphthylidene)-L-serine

作     者：YU Qing LI Chun-Ying BIAN He-Dong HUANG Fu-Ping LIANG Hong 

作者机构：College of Chemistry and Chemical EngineeringGuangxi Normal University Guilin 541004 China 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2006年第25卷第8期

页      面：915-918页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070304[理学-物理化学(含∶化学物理)] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：Supported by the Science Foundation of Guangxi Province (No. 0342025)  the Youth Science Foundation of Guangxi (No. 0542020) and the Teaching and Research Award Program for Outstanding Young Teachers in Higher Education Institutions of MOE  China 

主　　题：Schiff base Zn(Ⅱ) complex crystal structure 

摘      要：A new Zn（Ⅱ） complex, [Zn（L）2（H2O）2], where H2L = N-（2-hydroxy-1-naphthyli- dene）-L-sedne, has been synthesized and characterized by single-crystal X-ray diffraction. The crystal belongs to monoclinic system, space group C2/c with a = 13.669（2）, b = 6.4657（9）, c = 31.463（5） A, β = 98.010（2）°, V = 2753.6（7） A^3, Z = 8, Mr = 358.64, Dc = 1.730 g/cm^3, F（000） = 1472,μ（MoKa） = 1.814 mm^-1, the final R = 0.0355 and wR = 0.0706. The Zn（Ⅱ） atom adopts a square-pyramidal geometry coordinated by the tridentate ligand and two water molecules. Intermolecular hydrogen bonds link the complex molecules into a two-dimensional layer.