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Synthesis and aggregation properties of amphiphilic mono and bisadducts of fullerene in aqueous solution

Synthesis and aggregation properties of amphiphilic mono and bisadducts of fullerene in aqueous solution

作     者:Pu Zhanga Zhi Xin Guo Shuang Lv 

作者机构:Department of Chemistry Renmin University of China Beijing 100872 China Department of Chemistry Beijing Institute of Technology Beijing 100081 China 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2008年第19卷第9期

页      面:1039-1042页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 

基  金:the National Natural Science Foundation of China(No.20503039) the Scientinc Research Starting Foundation of Department of Chemistry,Renmin University of China 

主  题:Fullerene Aggregation Amphiphilic 

摘      要:New amphiphilic[60]fullerene monoadduct TPF and bisadducts BTPF were synthesized and well-characterized. Their aggregation properties in aqueous solution was investigated by UV-vis and TEM methods. In aqueous solution, monoadduct TPF forms irregularly shaped and some rod-like aggregates, whereas bisadducts BTPF gives sphadcal aggregates with diameters of 50-150 rim. It indicated that the aggregation properties of amphiphilic fullerene derivatives depend on the number of hydrophilic

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