RE-DISTRIBUTION OF THE N-METHYL GROUP IN GELSEMINE
RE-DISTRIBUTION OF THE N-METHYL GROUP IN GELSEMINE出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:1993年第4卷第3期
页 面:209-212页
核心收录:
主 题:RE DISTRIBUTION OF THE N METHYL GROUP IN GELSEMINE
摘 要:The N_(b)-bromomethyl derivative (2) of gelsemine,a quaternary ammonium salt,was found to be recalcitrant toward Hofmann type alkaline degradation which has been successful in other ***,a re-distribution of the N-methyl group took place,giving rise to 3a,1,3b and 3c,in descending order of R_f values.