XPS analysis and combustibility of residues from two coals extraction with sub-and supercritical water
XPS analysis and combustibility of residues from two coals extraction with sub-and supercritical water作者机构:State Key Laboratory of Fine Chemicals Institute of Coal Chemical EngineeringSchool of Chemical Engineering Dalian University of Technology Dalian 116012 China
出 版 物:《燃料化学学报》 (Journal of Fuel Chemistry and Technology)
年 卷 期:2009年第37卷第4期
页 面:385-392页
核心收录:
学科分类:081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术]
基 金:National Natural Science Foundation of China(No.90410018,20576019,20776028) Key Program in Major Research Plan for the West of China
摘 要:Two kinds of residues,obtained from extraction of one weakly reductive coal,Shenfu-Dongsheng coal(SD),and one reductive coal,Pingshuo coal(PS),with sub-and supercritical water on a semi-continuous apparatus,were characterized by calorific value analysis and XPS analysis,and the combustion behaviors of residues were investigated by thermogravimetric *** results show that the residues have higher calorific value than raw coal samples,and SD residue has higher calorific value than PS residue.C-C,C-O and pyridinic nitrogen,pyrrolic nitrogen are the dominant form of C,O and N on the surface of raw coal samples and their extraction *** combustion behaviors of extraction residues show that the SD residue is more reactive and more easily burned than PS residue.