Synthesis and curing of a novel amino-containing phthalonitrile derivative

作     者：Ke Zeng Ke Zhou Wen Rui Tang Yan Tang Hong Fei Zhou Tao Liu Yi Peng Wang Hai Bing Zhou Gang Yang 

作者机构：State Key Laboratory of Polymer Materials Engineering College of Polymer Science and Engineering Sichuan University Chengdu 610065 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2007年第18卷第5期

页      面：523-526页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Phthalonitrfle derivative Amino group Self-promotion curing behavior 

摘      要：A novel phthalonitrile derivative containing an amino group, 3,5-bis（3,4-dicyanophenoxy）aniline （CPA）, was synthesized via a nucleophilic displacement of 4-nitrophthalonitrile and 5-aminoresorcinol hydrochloride. The structure of CPA was confirmed by Fourier transform infrared spectra （FT-IR） and nuclear magnetic resonance （^1H NMR）. Thermal analysis performed on CPA revealed that the novel phthalonitrile derivative showed a self-promotion curing behavior and the resulting polymer exhibited outstanding heat-resistance.