Synthesis, Structure and Properties of Two New Coordination Polymers Based on 4-[（8-Hydroxy-5-quinolinyl）azo]-benzenesulfonic Acid
Synthesis, Structure and Properties of Two New Coordination Polymers Based on 4-[（8-Hydroxy-5-quinolinyl）azo]-benzenesulfonic Acid作者机构：State Key Laboratory of Urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150080 P. R. China State Key Laboratory of Inorganic Synthesis & Preparative Chemistry Jilin University Changchun 130012 P. R. China College of Chemical and Pharmaceutical Engineering Jilin Institute of Chemical Technology Jilin 132022 P. R. China
出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)
年 卷 期：2014年第30卷第1期
页 面：27-31页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 070301[理学-无机化学] 0702[理学-物理学]
基 金：Supported by the National Basic Research Program of China(No.2012CB821700) the Major International(Regional) Joint Research Project of National Natural Science Foundation of China(No.21120102034) the National Natural Science Foundation of China(No.20831002) and the Project of the Education Department of Jilin Province China(No.2013-328)
主 题：4-[(8-Hydroxy-5-quinolinyl)azo]-benzenesulfonic acid Solvothermal synthesis Coordination polymer Fluorescent property
摘 要：Two new coordination polymers based on 4-[（8-hydroxy-5-quinolinyl）azo]-benzenesulfonic acid（H2L）,{[CdL（H2O）2]·H2O}n（1） and {[CdL（en）]·EtOH}n（2）（en=ethylenediamine）,were solvothermally synthesized and structurally characterized by single-crystal X-ray *** 1 and 2 exhibit infinite 1D ladder-shaped chain structures,which are isostructural except that the two coordinating water molecules in compound 1 were replaced by one en molecule in compound 2 due to the use of different organic *** 1 and 2 were constructed into different supramolecular frameworks by hydrogen bonding and π…π stacking *** addition,the fluorescent properties of compounds 1 and 2 were ***,they were also investigated via IR spectral analysis,elemental analysis,powder X-ray diffraction（PXRD） and thermogravimetric analysis（TGA）.
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