Study on the Miscibility and Phase Behavior of Polyoxymethylene with Novolak

作     者：Xiaodong WANG, Hangquan LI and Riguang JIN (School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China) 

作者机构：School of Materials Science and Engineering Beijing University of Chemical Technology Beijing 100029 China 

出 版 物：《Journal of Materials Science & Technology》 (材料科学技术（英文版）)

年 卷 期：2000年第16卷第4期

页      面：427-430页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：教育部高等学校骨干教师资助计划 

主　　题：POM Study on the Miscibility and Phase Behavior of Polyoxymethylene with Novolak 

摘      要：The miscibility and phase behavior of the blends of polyoxymethylene (POM)/Novolak were investigated by the cloud point method, which showed that the POM/Novolak blends exhibited a lower critical solution temperature. The melting point of POM decreased when diluted with Novolak. From the melting temperature depression of POM, a negative interaction parameter (x) between POM and Novolak was obtained. The IR spectrum revealed that the miscibility between POM and Novolak was caused by the specific interaction between the OH groups of Novolak and the ether oxygen atoms of POM. The morphology of the blends investigated by polarized light microscopy showed that the size of spherulites of POM was sharply decreased by its mixing with Novolak. This suggests that Novolak be used as a compatibilizer for POM.