银纳米颗粒的合成及用于抗癌药氟他胺的电化学检测（英文）

作     者：Farzaneh Ahmadi Jahan Bakhsh Raoof Reza Ojani Mehdi Baghayeri Moslem Mansour Lakouraj Hamed Tashakkorian 

作者机构：Electroanalytical Chemistry Research LaboratoryDepartment of Analytical ChemistryFaculty of ChemistryUniversity of MazandaranBabolsarIran Department of Organic ChemistryFaculty of ChemistryUniversity of MazandaranBabolsarIran 

出 版 物：《催化学报》 (Chinese Journal of Catalysis)

年 卷 期：2015年第36卷第3期

页      面：439-445页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 0703[理学-化学] 070301[理学-无机化学] 

主　　题：电化学检测 银纳米粒子 氟他胺 抗癌药物 合成 Ag纳米粒子 修饰玻碳电极 电化学还原 

摘      要：Ag nanoparticles were synthesized on the surface of a glassy carbon electrode modified with p‐tert‐butylcalix[4]arene and p‐tert‐butylcalix[6]arene by the deposition of Ag+ at an open circuit potential followed by the electrochemical reduction of the Ag+.The presence of the calixarene layer on the electrode surface controlled the particle size and prevented *** voltam‐metry showed that the Ag nanoparticles on the modified glassy carbon electrode had good catalytic ability for the reduction of *** effects of calixarene concentration,potential applied for the reduction of Ag+,number of calixarene layers,and p H value on the electrocatalytic activity of the Ag nanoparticles were *** modified electrode had a linear range in differential pulse voltammetry of 10-1000 μmol/L with a detection limit of 9.33 μmol/L for flutamide at an S/N = *** method was applied to the detection of flutamide in practical samples.