Hot Corrosion Behaviour of Yttria-Stabilised Zirconia as Plasma Sprayed Coated Boiler Steel in Air and Salt at 900°C under Cyclic Condition
Hot Corrosion Behaviour of Yttria-Stabilised Zirconia as Plasma Sprayed Coated Boiler Steel in Air and Salt at 900°C under Cyclic Condition作者机构:HEEP Bharat Heavy Electricals Ltd. (Government of India Undertaking) Haridwar India. Metallurgical & Materials Engineering Department Indian Institute of Technology RoorkeeIndia
出 版 物:《Journal of Minerals and Materials Characterization and Engineering》 (矿物质和材料特性和工程(英文))
年 卷 期:2011年第10卷第5期
页 面:463-478页
学科分类:080503[工学-材料加工工程] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)]
主 题:Hot corrosion T-22 Plasma spray coating.
摘 要:Yttria-Stabilised Zirconia (YSZ) coatings were deposited on a T-22 boiler steel. NiCrAlY was used as bond coat and YSZ as top coat. Hot corrosion studies were conducted on uncoated as well as plasma spray coated specimens in air as well as salt (75 wt.% Na2SO4 + 25 wt.% NaCl) at 900°C under cyclic conditions. The thermogravimetric technique was used to establish kinetics of corrosion. X-ray diffraction (XRD) and scanning electron microscopy/energy-dispersive x-ray analysis (SEM/EDAX) techniques were used to analyse the corrosion products. This YSZ overlay coatings enhance resistance to corrosion significantly which can be attributed to formation of zirconium oxides (ZrO2) and yttrium oxide (Y2O3). This coating was more effective in salt environment and there is an extra phase of ZrS.