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Cu(II) Complex of L-Leucine Favor a Different Type of Crystal Structure from Cu(II)-L-Val and Cu(II)-L-Ile

Cu(II) Complex of L-Leucine Favor a Different Type of Crystal Structure from Cu(II)-L-Val and Cu(II)-L-Ile

作     者:Masaaki Yokota Shingo Kikuchi Jun Sen Toshimichi Kamei Norihito Doki Masaaki Yokota;Shingo Kikuchi;Jun Sen;Toshimichi Kamei;Norihito Doki

作者机构:Department of Chemistry and Bioengineering Iwate University Morioka Japan Research Institute for Bioscience Products & Fine Chemicals Ajinomono Co. Inc. Kawasaki Japan 

出 版 物:《Advances in Chemical Engineering and Science》 (化学工程与科学期刊(英文))

年 卷 期:2016年第6卷第1期

页      面:62-66页

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主  题:Crystallization Crystal Structure Copper Complex Branched Chain Amino Acid 

摘      要:Crystallization behavior of Cu(II) complexes of branched chain amino acids (BCAAs) has been studied. Mixing of Cu(II) and L-leucine in solution caused immediate precipitation of Cu(II)-L-Leu complex, while no precipitants were obtained when L-Val or L-Ile were used as ligands. These results are discussed based on structure differences among the precipitants.

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