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Phosphate Sorption in Water by Several Cationic Polymer Flocculants

Phosphate Sorption in Water by Several Cationic Polymer Flocculants

作     者:Timothy S. Goebel Robert J. Lascano Todd A. Davis Timothy S. Goebel;Robert J. Lascano;Todd A. Davis

作者机构:Cropping Systems Research Laboratory USDA-ARS Lubbock TX USA Department of Chemistry United States Air Force Academy Colorado Springs CO USA 

出 版 物:《Journal of Agricultural Chemistry and Environment》 (农业化学和环境(英文))

年 卷 期:2016年第5卷第1期

页      面:45-51页

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 

主  题:Polymer Flocculants Phosphate Sorption Polyacrylamides Poly (DADMAC) Smectite 

摘      要:Although inorganic phosphate is an essential plant nutrient, elevated levels in surface waters lead to adverse effects in the environment. These effects are attributed to runoff from rain or irrigation events that may cause the sorbed phosphate to be transported from the application sites and to move into neighboring watersheds. Increased phosphate concentration in watersheds may lead to a variety of environmental problems including increased algal blooms, bacterial contamination, and in some cases eutrophication. To overcome these effects, polymer flocculants have been shown to reduce the phosphate concentration in water by removing suspended solids and thereby removing the phosphate sorbed to the solids. The purpose of this study is to determine the amount, if any, of phosphate removed by several commercial polymers. The polymers chosen include the polyacrylamides Magnifloc 494C, Magnifloc 985N and Poly (diallyldimethyl ammonium chloride) (Poly (DADMAC)). Using these polymers, it is discovered that the positive charge density of the polymers affects the amount of phosphate removed from solution with Poly (DADMAC) (having 100% positive charge density) removing 40% of the phosphate from a solution containing 10 ppm phosphate.

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