Hexanuclear Complex of Platinum(II) with Cleavage Product of Cystamine Dihydrochloride by β-Mercaptoethylamine
Hexanuclear Complex of Platinum(II) with Cleavage Product of Cystamine Dihydrochloride by β-Mercaptoethylamine作者机构：The Institute of Catalysis and Inorganic Chemistry Named after Acad. M. F. Nagiyev of the National Academy of Sciences Azerbaijan Baku Azerbaijan
出 版 物：《Advances in Chemical Engineering and Science》 (化学工程与科学期刊（英文）)
年 卷 期：2016年第6卷第1期
页 面：29-33页
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
主 题：Mercaptoamine Ligands Platinum Six-Nuclear Complexes Synthesis
摘 要：Six-nuclear complexes of Platinum(II) with cleavage of a cystamine dihydrochloride by β-mercaptoethylamine with composition [Pt6(H2NCH2CH2S)8]Cl4·5H2O had been syntesized for the first time. Structure of the complex had been installed together with IKS- and XRD analysis. It has been established that each atom of platinum is surrounded by two atoms of sulfur and nitrogen due to bidentate coordination of a ligand. Only two of the six platinum atoms are on the same plane;other four atoms are in the different crossing planes. Four platinum atoms form adurable metal chelate cycles, which collapse over temperature 260℃. The results of IR spectroscopy confirmed with the RS-analysis.
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