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Photocatalytic Degradation of Ibuprofen Using TiO<sub>2</sub>and Ecotoxicological Assessment of Degradation Intermediates against <i>Daphnia similis</i>

Photocatalytic Degradation of Ibuprofen Using TiO<sub>2</sub>and Ecotoxicological Assessment of Degradation Intermediates against <i>Daphnia similis</i&gt

作     者:Farley S. Braz Milady R. A. Silva Flávio S. Silva Sandro J. Andrade Ana L. Fonseca Márcia M. Kondo 

作者机构:Natural Resource Institute Universidade Federal de Itajubá Itajubá Brazil Physic and Chemistry Institute Universidade Federal de Itajubá Itajubá Brazil 

出 版 物:《Journal of Environmental Protection》 (环境保护(英文))

年 卷 期:2014年第5卷第7期

页      面:620-626页

学科分类:07[理学] 0703[理学-化学] 

主  题:Photodegradation TiO2 Ibuprofen Acute Toxicity 

摘      要:Several pharmaceutical compounds have been detected in natural aqueous systems and ibuprofen (IBF), one of the most consumed medicament, has been detected in many countries. The degradation efficiency of IBF under TiO2/UV radiation was evaluated. Optimum degradation results were observed using 20 mg·L-1 of TiO2, pH 7.8 and 5 mg·L-1 of IBF. Under these experimental conditions total IBF removal was achieved in less than 60 min of irradiation. Although total IBF concentration was observed, the total mineralization of the compound was not achieved. The by-products generated during TiO2/UV reaction showed to be more toxic against Daphnia similis than the initial IBF present in aqueous solution.

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