Study on the reaction of C60 with DL-valine and cyclohexanone

作     者：Zheng, DG Li, YL Mao, Z Zhu, DB 

作者机构：CHINESE ACAD SCIINST CHEMBEIJING 100080PEOPLES R CHINA 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1996年第14卷第6期

页      面：555-560页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Project supported by the National Natural Science Foundation of China 

主　　题：C-60 1,3-dipolar cycloaddition reaction fulleropyrrolidine 

摘      要：Reaction of C-60 with DL-valine and cyclohexanone in refluxing chlorobenzene under N-2 yields three [60]fulleropyrrolidine derivatives (mono-, bis- and triadduct) which are characterised on the basis of spectroscopies and cyclic voltammetry. It is found that the ratio of the three products greatly depends on the reaction conditions.