Electroreduction of Dy^(3+) on Ni Cathode in Molten Chlorides
Electroreduction of Dy ̄(3+) on Ni Cathode in Molten Chlorides作者机构:Department of Chemistry Zhongshan University Guangzhou 510275 China
出 版 物:《Journal of Rare Earths》 (稀土学报(英文版))
年 卷 期:1996年第14卷第4期
页 面:271-274页
核心收录:
学科分类:0709[理学-地质学] 0819[工学-矿业工程] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0708[理学-地球物理学] 0703[理学-化学] 070301[理学-无机化学]
主 题:Electroreduction Dy-Ni alloy Dy NaCl-KCl-DyCl_3
摘 要:The cyclic voltammetry,electrode potential-time curve after potentiostatic electrolysis,potential-step method and X-ray diffraction were used to study the electrochemical reaction of Dy ̄(3+) in equimolar NaCl-KCl mixture on Ni *** DyNi5 forms at first and then the intermetallic compounds of Dy-Ni containing more Dy form in *** metallic Dy deposits at *** Dy-Ni alloy was prepared by consumable cathode in molten *** Dy-Ni alloy contained Dy over 85 wt% was *** composition of alloy was DyNi5 and *** current efficiency and the recovery of Dy were near 80%.