A novel and efficient synthesis of alkyl thiocyanates from alkyl halides in water using phase transfer catalysts

作     者：Maryam Gorjizadeh Soheil Sayyahi 

作者机构：Department of Chemistry Islamic Azad University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2011年第22卷第6期

页      面：659-662页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Shushtar University Research Council 

主　　题：Alkyl thiocyanate Alkyl halide 1 4-Bis(triphenylphosphonium)-2-butene dichloride 1 4-Bis(triphenyl-phosphonium)-2-butene dithiocyanate Phase transfer catalyst 

摘      要：1,4-Bis（triphenylphosphonium）-2-butene dichloride（BTPBDC） and 1,4-bis（triphenyl phosphonium）-2-butene dithiocyanate （BTPBDT） were prepared and used as phase-transfer *** halides were converted efficiently to the corresponding alkyl thiocyanates under mild reaction conditions in *** evidence for the formation of isothiocyanates as by-product of the reaction was observed.