水杨醛缩乙醇胺双氧钒席夫碱配合物的合成、晶体结构及热分解研究(英文)

作     者：李连之 许涛 王大奇 冀海伟 

作者机构：聊城大学化学化工学院聊城252059 

出 版 物：《无机化学学报》 (Chinese Journal of Inorganic Chemistry)

年 卷 期：2004年第20卷第2期

页      面：236-240页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：聊城大学科学基金资助项目 

主　　题：水杨醛缩乙醇胺 席夫碱 双氧钒配合物 合成 晶体结构 热分解 

摘      要：A new complex bis[(N-salicylidene-N’-ami noethanol)abstract:dioxovandium (Ⅴ)abstract:,[V (Ⅴ)abstract:(Ⅴ)abstract:(SALAE)abstract:]2 ,was synthesized by the reaction of salicylaldehyde and aminoethanol with va nadyl *** was characterized by elemental analysis,IR and X-ray single cr ystal diffraction *** crystal of the title complex(C 18 H 20 N 2 O 8 V 2 ,M r =494.24)abstract:be-longs to monoclinic,space group P2 1 /c with the following crystallographic parameters:a=1.7966(6)abstract:nm,b=0.7587(3)abstract:n m,c=2.1539(7)abstract:nm,β =92.551(6)abstract:°,V=2.9329(17)abstract:nm 3 ,Z=6,D c =1.679g · cm -3 ,μ (MoK α )abstract:=1.006mm -1 ,F(000)abstract:=1512,and final R 1 =0.0563,wR 2 =0.1243for observed reflections2861(I2 σ (I)abstract:)abstract:.The complex is a bis( μ -oxo)abstract:-bridged V schiff base dimer formed by two dioxovandium units,V is six-coordinated and forms a distorted octahedral *** thermal d ecomposition for the complex was studied by TG-DTG curves and the apparent acti vation energy was obtained by the Kissinger ***:211147.