Synthesis,Crystal Structure and Luminescence of a New Zn(Ⅱ) Complex [Zn(1,2,3-HBTC)(L)]_2 Constructed by Mixed Ligands

作     者：WANG Xiu-Yan ZHAO Zhong-Yu LIU Rui XU Ye LI Xin-Hang XU Zhan-Lin 

作者机构：Key Laboratory of Preparation and Applications of Environmental Friendly MaterialsJilin Normal University Department of ChemistryJilin Normal University 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2015年第34卷第5期

页      面：725-728页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：Supported by the Institute Foundation of Siping City(No.2013036) 

主　　题：hydrogen bonds crystal structure dimer 1 2 3-benzentricarboxylic acid 

摘      要：A new Zn（Ⅱ） complex,[Zn（1,2,3-HBTC）（L）]2（1,L = 2-（2-chloro-6-fluorophenyl）-1H-imidazo[4,5-f][1,10]phenanthroline and 1,2,3-H3 BTC = 1,2,3-benzentricarboxylic acid）,was synthesized under hydrothermal conditions and characterized by single-crystal X-ray *** crystallizes in triclinic,space group P1 with a = 10.455（2）,b = 11.533（2）,c = 12.499（3） A,α = 116.97（3）,β = 94.08（3）,γ = 103.29（3）o,V = 1280.2（4） A^3,Z = 1,C56H28Cl2F2N8O12Zn2,Mr = 1244.50,Dc = 1.614 g/cm^3,F（000） = 628,μ（Mo Ka） = 1.124 mm^-1,R = 0.0502 and w R = *** compound 1,two 1,2,3-HBTC anions bridge two Zn（Ⅱ） atoms to give a dimeric structure with Zn···Zn distance of 3.15 *** dimers interact through π-π stackings between two L ligands to result in a supramolecular ***,N–H···O and O–H···N hydrogen bonds further stabilize the 2D supramolecular architecture of *** addition,the luminescent property of 1 has been studied.