Electrochemical performance of microarc oxidation films formed on AZ91D alloy in two group electrolytes

作     者：王立世 蔡启舟 魏伯康 刘全心 

作者机构：State Key Laboratory of Die and Mould Technology Huazhong University of Science and Technology 

出 版 物：《中国有色金属学会会刊：英文版》 (Transactions of Nonferrous Metals Society of China)

年 卷 期：2005年第15卷第4期

页      面：777-783页

核心收录：

学科分类：080503[工学-材料加工工程] 0806[工学-冶金工程] 08[工学] 0818[工学-地质资源与地质工程] 0815[工学-水利工程] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0813[工学-建筑学] 0814[工学-土木工程] 0702[理学-物理学] 

基　　金：Project(2002ABB051) supported by the Natural Science Foundation of Hubei Province and the Research Foundation ofHUST  China 

主　　题：有色金属 电化学 AZ91D合金 氧化反应 

摘      要：The phase composition and electrochemical performances of microarc oxidation（MAO） films prepared on AZ91D alloy by using step-down current method in a phosphate electrolyte（P-film） and silicate electrolyte（Si-film） were studied. The results show that P-film is mainly composed of Mg, MgAl2O4 and MgO, and Si-film is composed of Mg2SiO4 and MgO. There clearly exists a fluoride-enriched zone with the thickness of about 12μm for P-film and 0.71μm for Si-film at the MAO coating/substrate interface. The electrochemical tests show that both P-film and Si-film can enhance the corrosion resistance of AZ91D magnesium alloy significantly. The corrosion failure process of the two films in 5%（mass fraction） NaCl solution is quite different.