NOVEL REACTIONS BETWEEN CHROMIUM CARBYNE COMPOUNDS AND DICOBALT OCTACRBONYL

作     者：Hong Sui SUN Yuan Qi YIN Xiao Zeng YOU and Yong Jiang LIU.(State key laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University,Nanjing 210093)(Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 7 

作者机构：Nanjing Univ Inst Coordinat Chem State Key Lab Coordinat Chem Nanjing 210093 Peoples R China Chinese Acad Sci Lanzhou Inst Chem Phys Lanzhou 730000 Peoples R China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1995年第6卷第12期

页      面：1069-1072页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

摘      要：The carbyne compounds(1), and (bipy=α,α -dipyridyl) (2) react with dicobalt octacarbonyl in dichloromethane at room temperature, after chromatography on silica gel column, to give compounds [Co3(μ3-CC6H5)(CO)9] (3),[Co2Cr(μ3-CC6H5)Br(CO)8(Py)2] (4), and [Co2Cr(μ3-CC6H5)Br(CO)8(bipy)](5). Their structures were deduced from elemental analyses, IR, HNMR, 13C-{1H}NMR, and mass spectra.