A colorimetric and fluorometric fluoride sensor based on a BODIPY-phenol conjugate

作     者：LV YongJun XU Jian GUO Yong SHAO ShiJun 

作者机构：Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu ProvinceLanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical PhysicsChinese Academy of SciencesLanzhou 730000China Graduate University of the Chinese Academy of SciencesChinese Academy of SciencesBeijing 100039China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2011年第54卷第5期

页      面：797-801页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：supported by the National Natural Science Foundation of China (20972170 to S-J. Shao) the open fund of State Key Laboratory of Oxo Synthesis & Selective Oxidation (OSSO2008kjk6 to S-J. Shao) the Natural Science Foundation of Gansu Province (096RJ2A033 to Y. Guo) 

主　　题：colorimetric fluorescence fluoride sensor BODIPY 

摘      要：A boradiazaindacenes (BODIPY)-phenol conjugate,1,can act as a colorimetric and fluorometric sensor for sensitive and se-lective measurement of F-over AcO-and H2PO-4 in CH3CN. Sensor 1 gives response to F-in a 1:1 ratio via the deprotonation of the phenolic OH proton,which results in color change from pale yellow to light green and quenching of bright green fluo-rescence.