Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates InvoIving Sequential Olefins Insertion and Borylation Reaction
作者机构:Key Laboratory of Functional Molecular Engineering of Guangdong ProvinceSchool of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhouGuangdong 510640China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2019年第37卷第2期
页 面:140-147页
核心收录:
基 金:the National Program on Key Research Project (No. 2016YFA0602900) the National Natural Science Foundation of China (No. 21420102003) the Guangdong Province Science Foundation (No. 2017B090903003) for financial support
主 题:Palladium-Catalyzed Three-Component Coupling Reaction Allyl Carboxylates
摘 要:Summary of main observation and conclusion An efficient Pd-catalyzed three-component coupling reaction of allyl carboxylates, norbornenes and diboronates is described, which allows efficient assembly of C(sp3)-C(sp3) and C(sp3)-B bonds in a single process. Moreover, this approach shows advantages of good chemo- and regioselectivity, as well as good substrates suitability.