Palladium-Catalyzed Three-Component Coupling Reaction of Allyl Carboxylates, Norbornenes and Diboronates InvoIving Sequential Olefins Insertion and Borylation Reaction

作     者：Zun Li Jia Zheng Chunsheng Li Wanqing Wu Huanfeng Jiang 

作者机构：Key Laboratory of Functional Molecular Engineering of Guangdong ProvinceSchool of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhouGuangdong 510640China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2019年第37卷第2期

页      面：140-147页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：the National Program on Key Research Project (No. 2016YFA0602900) the National Natural Science Foundation of China (No. 21420102003) the Guangdong Province Science Foundation (No. 2017B090903003) for financial support 

主　　题：Palladium-Catalyzed Three-Component Coupling Reaction Allyl Carboxylates 

摘      要：Summary of main observation and conclusion An efficient Pd-catalyzed three-component coupling reaction of allyl carboxylates, norbornenes and diboronates is described, which allows efficient assembly of C(sp3)-C(sp3) and C(sp3)-B bonds in a single process. Moreover, this approach shows advantages of good chemo- and regioselectivity, as well as good substrates suitability.