Samarium Diiodide-Induced Reductive Cleavage of Se-St Bond in Arylselenotrimethylsilane Leading to the Formation of Samarium Arylselenolate: Synthesis of β-Arylseleno Estsrs and β-Arylseleno Nitriles

作     者：Song Lin ZHANG and Yong Min ZHANG(Department of Chemistry, Hangzhou University, Hangzhou, 310028) 

作者机构：Department of Chemistry Hangzhou University Hangzhou 310028 China 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1998年第9卷第10期

页      面：885-887页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

主　　题：samarium diiodide arylselenotrimethylsilane arylseleno esters arylseleno nitriles 

摘      要：The Se-St bond in arylselenotrimethylsilane was reduced by samarium diiodide to produce samarium arylselenolate, which reacted with a,β-unsaturated esters or α,β-unsaturated nitriles to give β-selenoesters and β-selenonitriles, respectively.