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Impedance Characterization of the Film Formation Process at the Graphite Anodes

Impedance Characterization of the Film Formation Process at the Graphite Anodes

作     者:Bo Hua DENG Yong Fang LI Hua Quan YANG 

作者机构:Center for Molecular ScienceInstitute of ChemistryChinese Academy of SciencesBeijing 100080 Department of ChemistryPeking UniversityBeijing 100875 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2000年第11卷第10期

页      面:915-918页

核心收录:

学科分类:081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 

基  金:the National 863 project (KJ951-A1-501) 

主  题:electrochemical impedance spectroscopy surface film graphite anodes Li-ion battery 

摘      要:In this paper, the formation mechanism of the passive SEI film at the natural graphite anodes was investigated with tilt: electrochemical impedance spectroscopy (EIS). A characteristic semicircle was observed in the lower frequency range of the EIS spectrum for the irreversible charge process (lithium intercalation) at ca. 0.75V, 0.40V and 0.20V.

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