Studies on the Interactions between Potassium oxalato-oxodiperoxovanadate and Histidine by NMR and MS

作     者：Jian Liang YE Xing Wang ZHOU Zhong CHEN Zhi Wei CHEN Pei Qiang HUANG 

作者机构：Department of ChemistryXiamen UniversityXiamen 361005 Department of BiologyXiamen UniversityXiamen 361005 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2001年第12卷第11期

页      面：987-988页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070302[理学-分析化学] 0703[理学-化学] 

基　　金：国家自然科学基金 

主　　题：oxalato-oxodiperoxovanadate histidine peroxovanadium NMR ESI-MS 

摘      要：Multi-nuclear NMR and ESI-MS have been applied to study the interactions between oxalato-oxodiperoxovanadate and histidine in neutral solution. Coordination between the complex and histidine was monitored by V-51 NMR. A pair of new isomers produced via vanadium atom binding separately to N1 and N3 of the imidazole ring of histidine was characterized by several spectroscopic methods. Experimental results show that the structure activity relationship of peroxovanadium complexes bearing organic ligands may be related to the specific recognition between peroxovanadium and histidine residue of tyrosine phosphatase.