Detoxification of ferrocyanide in a soil–plant system
Detoxification of ferrocyanide in a soil–plant system作者机构：Brandenburg University of Technology Cottbus-Senftenberg
出 版 物：《Journal of Environmental Sciences》 (环境科学学报（英文版）)
年 卷 期：2019年第31卷第3期
页 面：54-64页
核心收录：
学科分类：07[理学] 09[农学] 0903[农学-农业资源与环境] 0713[理学-生态学]
主 题：Iron cyanide Detoxification Exposure Phytoremediation
摘 要：The detoxification of iron cyanide in a soil–plant system was investigated to assess the total cyanide extracted from contaminated soil and allocated in the leaf tissue of willow trees(Salix caprea). They were grown in soil containing up to 1000 mg/kg dry weight(dw) of cyanide(CN),added as ^(15)N-labeled potassium ferrocyanide and prepared with a new method for synthesis of labeled iron cyanides. CN content and ^(15)N enrichment were monitored weekly over the exposure in leaf tissue of different age. The ^(15)N enrichment in the young and old leaf tissue reached up to 15.197‰ and 9063‰, respectively; it increased significantly over the exposure and with increasing exposure concentrations(p 0.05). Although the CN accumulation in the old leaf tissue was higher, compared to the young leaf tissue(p 0.05), the ^(15)N enrichment in the two tissue types did not differ statistically. This indicates a non-uniform CN accumulation but a uniform ^(15)N allocation throughout the leaf mass. Significant differences were detected between the measured CN content and the C^(15)N content, calculated from the ^(15)N enrichment(p 0.05), revealing a significant CN fraction within the leaf tissue, which could not be detected as ionic CN. The application of labeled iron CN clearly shows that CN is detoxified during uptake by the willows. However, these results do not exclude other detoxification pathways, not related to the trees. Still, they are strongly indicative of the central role the trees played in CN removal and detoxification under the experimental conditions.
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