Studies on Synthesis and Photochromism of a Novel Class of Fulgimide: (Z)-4-Oxazolylfulgimide

作     者：肖军平 韩勇 陈懿 李文 樊美公 

作者机构：Technical Institute of Physics and ChemistryChinese Academy of Sciences 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2004年第22卷第1期

页      面：100-102页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基　　金：the National Science Foundation of China (Nos. 29832030 and 60277001) and Chinese National Key Research Project (No. G1999033005) 

主　　题：Z)-4-oxazolyl fulgimide synthesis photochromism 

摘      要：A novel class of fulgimide, (Z)-4-oxazolylfulgimide ((Z)-1-benzyl-4-isopropylidene-3-[1-(2-aryl-5-methyl-oxazolyl)ethylidene]tetrahydropyrrole-2,5-dione), was synthesized by the reaction of (Z)-4-oxazolyl fulgide (4-isopropylidene-3-[1-(2-aryl-5-methyloxazolyl)ethylidene]tetrahydrofuran-2,5-dione) with benzyl amine. Photo-chromic property of (Z)-4-oxazolylfulgimide was studied. Compared with (Z)-4-oxazolylfulgide, the absorption maximum of the colored form of (Z)-4-oxazolylfulgimide is bathochromic-shifted. Substituents on the aryl ring af-fect the absorption maximum of the open form and the colored form of (Z)-4-oxazolylfulgimide.