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Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper electrode

Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper electrode

作     者:XU Wenying GAO Tingyao ZHOU Rongfeng MA Lumin 

作者机构:The National Engineering Research Center for Urban Pollution ControlTongji UniversityShanghai 200092China 

出 版 物:《Frontiers of Environmental Science & Engineering》 (环境科学与工程前沿(英文))

年 卷 期:2007年第1卷第2期

页      面:207-212页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:This work was supported by the National High-Tech Research and Development(863)Program of China(Grant No.2002AA601270) 

主  题:chlorinated hydrocarbons cyclic voltammetry electrochemical reduction copper electrode 

摘      要:The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltam-metry *** reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode were *** relationship between the structure of chlori-nated hydrocarbons and their reductive activity were *** experimental results showed that chlorinated alkanes and a portion of chlorinated aromatic hydrocarbons could be reduced directly at the copper ***,chlorinated aromatic hydrocarbons were not easy to reduce at the copper *** results provided a theoretical basis for the catalyzed iron inner electrolysis method.

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