Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper electrode
Electrochemical reduction characteristics and the mechanism of chlorinated hydrocarbons at the copper electrode作者机构:The National Engineering Research Center for Urban Pollution ControlTongji UniversityShanghai 200092China
出 版 物:《Frontiers of Environmental Science & Engineering》 (环境科学与工程前沿(英文))
年 卷 期:2007年第1卷第2期
页 面:207-212页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
主 题:chlorinated hydrocarbons cyclic voltammetry electrochemical reduction copper electrode
摘 要:The electrochemical reduction characteristics of chlorinated hydrocarbons were investigated by cyclic voltam-metry *** reduction mechanism and activity of the chlorinated hydrocarbons at the copper electrode were *** relationship between the structure of chlori-nated hydrocarbons and their reductive activity were *** experimental results showed that chlorinated alkanes and a portion of chlorinated aromatic hydrocarbons could be reduced directly at the copper ***,chlorinated aromatic hydrocarbons were not easy to reduce at the copper *** results provided a theoretical basis for the catalyzed iron inner electrolysis method.