Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis
Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis作者机构：College of Chemistry and Materials Engineering Wenzhou University Wenzhou Zhejiang 325035 China Department of chemistry Zhejiang University Hangzhou Zhejiang 310027China
出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)
年 卷 期：2018年第36卷第11期
页 面：1075-1109页
核心收录：
基 金：We thank the National Natural Science Foundation of China （No. 21772171） National 973 Program （No. 2015CB856600） the Fundamental Research Funds for the Central Universities （No. 2018QNA3009） and the ＂Thousand Youth Talents Plan＂ for finan- cial support.
主 题：hydrometallation the first row transition metals alkenes alkynes metal‐hydride
摘 要：Hydrometallation of alkenes and alkynes provides a straightforward route to access alkyl‐ or alkenyl‐metal reagents, which have a wide range of applications in organic transformations. In recent years, the first row transition metals (such as copper, nickel, cobalt, iron, etc .) have emerged high activity and selectivity in this area with the aid of a variety of ligands. This review covers the recent advances in the hydrometallation of minimally functionalized unsaturated C—C bonds (including alkenes, alkynes, dienes, allenes, enynes, etc .), as well as transformations involving catalytic hydrometallation process via the first row transition metal catalysis.
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