ESR Studies on N-Alkylphenothiazine Radical Cation Salts

作     者：Guo, Qing-xiang Liu, Bo Liu, You-cheng 

作者机构：LANZHOU UNIVNATL LAB APPL ORGAN CHEMLANZHOU 730000PEOPLES R CHINA UNIV SCI & TECHNOL CHINADEPT MODERN CHEMHEFEI 230006PEOPLES R CHINA 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：1995年第11卷第3期

页      面：195-201页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：Phenothiazine Radical cation salts. ESR spectra 

摘      要：he stable radical cation salts of phenothiazine and N-alkyl-phenothiazine(alkyl =methyl , ethyl , isohutyl , isopentyl and benzyl) hexachloroantimonate ,per-chlorate , and iodide were prepared by means of one-electron oxidation with 2 ,2 , 6 ,6-tetramethyl- 4-acetoxypiperidine oxoammonium hexachloroantimonate , perchloricacid, hydrogen peroxide, and molecular iodine, respectively. The radical cationswere characterized using ESR spectroscopy. Conformational analysis based on theESR parameters suggests that the radical cations adopt a planar configuration withthe nitrogen radical as the center.