Density and Excess Molar Volume of Binary Mixtures ofp-Xylene+Acetic Acid and o-Xylene+Acetic Acid at Different Temperatures and Pressures
Density and Excess Molar Volume of Binary Mixtures ofp-Xylene+Acetic Acid and o-Xylene+Acetic Acid at Different Temperatures and Pressures作者机构:School of Chemical Engineering and Technology Tianjin University Tianjin 300072 China
出 版 物:《Chinese Journal of Chemical Engineering》 (中国化学工程学报(英文版))
年 卷 期:2008年第16卷第2期
页 面:247-255页
核心收录:
基 金:Supported by China Petrochemical Corporation(X505012)
主 题:density excess molar volume p-xylene o-xylene acetic acid
摘 要:A new apparatus was designed with a thick-walled glass capillary, electric heater tube with red copper and heat preservation. The thick-walled glass capillary was used for its advantages of resistance to acid corrosion and pressure, and ease of observation. The experimental densities over the entire range of mole fraction for the binary mixture of p-xylene+acetic acid and o-xylene+acetic acid were measured using the new apparatus at temperatures ranging from 313.15K to 473.15K and pressure ranging from 0.20 to 2,0 MPa. The density values were used in the determination of excess molar volumes, W. The Redlich-Kister equation was used to fit the excess molar volume values, and the coefficients and estimate ot the standard error values were presented. The experimental resuits prove that the density measurement apparatus is successful.