电解质对纳米银胶水溶液光谱行为的影响

作     者：郑爱国 王笃金 徐怡庄 吴瑾光 徐端夫 

作者机构：北京大学化学与分子工程学院稀土材料化学及应用国家重点实验室北京100871 中国科学院化学研究所高分子物理与化学国家重点实验室北京100080 中国科学院研究生院北京100039 

出 版 物：《高等学校化学学报》 (Chemical Journal of Chinese Universities)

年 卷 期：2003年第24卷第11期

页      面：1953-1955页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

基　　金：国家自然科学基金 (批准号 :2 0 15 10 0 4 5 0 2 0 3 0 0 1 5 973 3 0 60 5 9873 0 3 0 ) 高分子物理与化学国家重点实验室基金 (批准号 :0 1-B-0 8) 国家科技部"极端条件下物质的标准"(批准号 :2 0 0 1de A 2 0 0 2 3 -B) 稀土材料化学国家重点实验室主任基金 

主　　题：电解质 纳米银胶 水溶液 光谱行为 阴离子 阳离子 纳米材料 

摘      要：The interaction between electrolytes and nano-Ag particles were investigated by using UV-Vis spectroscopic method. Tetramethylammonium ion, which can be hardly adsorbed on nano-Ag because of its bulky methyl group, was used as the cation to study the variation of surface plasma resonance band of nano-Ag induced by various anions. No significant change of the band for nano-Ag could be observed when Cl - and Br - ions were introduced into nano-Ag sol. Based on the above results, different metal salts with Cl - as anion were used for investigating the spectra of nano-Ag. The nano-Ag sol exhibits a different spectral behavior when various metal ions were introduced.