Recent progress on the frontiers of polyoxometalates structures and applications
Recent progress on the frontiers of polyoxometalates structures and applications作者机构：State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical Technology
出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)
年 卷 期：2019年第62卷第2期
页 面：159-161页
核心收录：
基 金：supported by the National Key Research and Development Program of China (2017YFB0307303) the National Natural Science Foundation of China (U1707603, 21625101, 21521005, U1507102, 201808011) the National Basic Research Program of China (2014CB932104) Beijing Natural Science Foundation (2182047) Postdoctoral Science Foundation of China (2018M631313) the Fundamental Research Funds for the Central Universities (ZY1709)
主 题：Polyoxometalates discrete metal oxides
摘 要：Polyoxometalates (POMs),a class of discrete anionic metal oxides in groups V and VI,are constructed via the con- densation of metal oxide polyhedral (MOx,M=W^vI,Mo^vI, Vv,Nb,Ta,*** x=4-7)with each other in a comer-, edge-,or rarely in a face-sharing manner [1-3].Up to now, the broadening family of POM derivatives ranges from small size clusters to nanoscale giant aggregates,which have shown impressive chemical and physical properties and great potential in fields of catalysis,magnetism,medicine,photochemistry,environment,energy and materials science [4,5].Latest progress on POMs chemistry is directed to the construction of high-nnclearity clusters and the exploration of functional applications in energy chemistry,catalysis,and self-assembly (Figure 1).
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