Synthesis and catalytic properties of iron-cerium phosphate prepared in ethylene glycol using additives
作者机构:Department of Informatics and Environmental SciencesKyoto Prefectural University1-5Shimogamo Nakaragi-choSakyo-kuKyoto 606-8522Japan
出 版 物:《Journal of Advanced Ceramics》 (先进陶瓷(英文))
年 卷 期:2013年第2卷第1期
页 面:49-54页
核心收录:
学科分类:0808[工学-电气工程] 081704[工学-应用化学] 0809[工学-电子科学与技术(可授工学、理学学位)] 07[理学] 0817[工学-化学工程与技术] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0702[理学-物理学]
主 题:iron phosphate cerium substitution ethylene glycol ICP analysis catalytic property
摘 要:The effects of cerium substitution,use of additives,and heating temperature on the chemical composition and catalytic activity of iron phosphate were ***-cerium phosphate was prepared from iron nitrate,ammonium cerium nitrate,and sodium phosphate in ethylene glycol using sodium dodecyl-sulfate or acetylacetone as *** chemical composition,particle shape and size distribution of the obtained samples were respectively evaluated based on ICP and XRD,SEM,and laser diffraction/scattering *** catalytic activity was evaluated based on the decomposition of the complex formed from formaldehyde,ammonium acetate,and *** peaks corresponding to FePO_(4) were observed for the samples heated at 600℃whereas samples treated at lower temperatures were ***-cerium phosphates heated at 200℃and 400℃exhibited high catalytic activity for the decomposition of the aforementioned complex.