Al(HSO_4)_3/silica gel as a novel catalytic system for the ring opening of epoxides with thiocyanate anion under solvent-free conditions

作     者：Ali Reza Kiasat Arash Mouradzadegun Somayeh Elahi Mehdi Fallah-Mehrjardi 

作者机构：Department of ChemistryCollege of ScienceShahid Chamran University 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2010年第21卷第2期

页      面：146-150页

核心收录：

学科分类：081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基　　金：the Shahid Chamran University Research Council for partial financial support of this work 

主　　题：Metal hydrogen sulfates Solid acid catalysts Ring opening of epoxides β-Hydroxy thiocyanates 

摘      要：For the first time,metal hydrogen sulfates and phosphates/silica gel have been studied as efficient and powerful solid acid catalysts in the ring opening of epoxides with thiocyanate *** most significant result was obtained by Al(HSO4)3/SiO2which afforded the corresponding β-hydroxy thiocyanates under mild reaction conditions and in very short reaction *** cheapness, availability of the catalyst,ease of procedure and work-up make this method attractive for the organic synthesis.