One-pot Synthesis of 6-Hydroxyhexanoic Acid from Cyclohexanone Catalyzed by Dealuminated HBEA Zeolite with Aqueous 30% H_2O_2 Solution

作     者：Xia Changjiu Yang Yongjia Zhao Yi Lin Min Zhu Bin Peng Xinxin Dai Zhenyu Luo Yibin Shu Xingtian 

作者机构：State Key Laboratory of Catalytic Materials and Reaction Engineering Research Institute of Petroleum Processing SINOPEC 

出 版 物：《China Petroleum Processing & Petrochemical Technology》 (中国炼油与石油化工（英文版）)

年 卷 期：2018年第20卷第3期

页      面：1-6页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 

基　　金：supported by the National Basic Research Program of China(973 Program,2006CB202508) the China Petrochemical Corporation Program(SINOPEC Group ST417004) the National Key Research and Development Program of China(2017YFB0306800) 

主　　题：Baeyer-Villiger oxidation cyclohexaxlone 6-hydroxyhexanoic acid zeolite hydrolysis 

摘      要：The one-pot synthesis of 6-hydroxyhexanoic acid from cyclohexanone via the integrated Baeyer-Villiger oxida-tion and ring opening reaction catalyzed by dealuminated HBEA zeolite has been developed. Under optimized conditions,the cyclohexanone conversion and 6-hydroxyhexanoic acid selectivity are over 95%, respectively. The excellent catalyticperformance is attributed to the activation of carbonyl group of cyclohexanone and the fast hydrolysis and ring opening ofs-caprolactone by both Lewis acid and Br0nsted acid sites under aqueous conditions.