One-pot Synthesis of 6-Hydroxyhexanoic Acid from Cyclohexanone Catalyzed by Dealuminated HBEA Zeolite with Aqueous 30% H_2O_2 Solution

作     者：Xia Changjiu Yang Yongjia Zhao Yi Lin Min Zhu Bin Peng Xinxin Dai Zhenyu Luo Yibin Shu Xingtian 

作者机构：State Key Laboratory of Catalytic Materials and Reaction Engineering Research Institute of Petroleum Processing SINOPEC 

出 版 物：《China Petroleum Processing & Petrochemical Technology》 (中国炼油与石油化工（英文版）)

年 卷 期：2018年第20卷第3期

页      面：1-6页

核心收录：

学科分类：0820[工学-石油与天然气工程] 0821[工学-纺织科学与工程] 081702[工学-化学工艺] 0808[工学-电气工程] 0817[工学-化学工程与技术] 08[工学] 0807[工学-动力工程及工程热物理] 0827[工学-核科学与技术] 0703[理学-化学] 0802[工学-机械工程] 0702[理学-物理学] 0801[工学-力学（可授工学、理学学位）] 

基　　金：supported by the National Basic Research Program of China(973 Program,2006CB202508) the China Petrochemical Corporation Program(SINOPEC Group ST417004) the National Key Research and Development Program of China(2017YFB0306800) 

主　　题：水解作用 H2O2 合成 催化 沸石 优化条件 路易斯酸 戒指 

摘      要：The one-pot synthesis of 6-hydroxyhexanoic acid from cyclohexanone via the integrated Baeyer-Villiger oxidation and ring opening reaction catalyzed by dealuminated HBEA zeolite has been developed. Under optimized conditions, the cyclohexanone conversion and 6-hydroxyhexanoic acid selectivity are over 95%, respectively. The excellent catalytic performance is attributed to the activation of carbonyl group of cyclohexanone and the fast hydrolysis and ring opening of ε-caprolactone by both Lewis acid and Br?nsted acid sites under aqueous conditions.