PmClAn基膜修饰电极的电化学及催化性质研究

作     者：戴李宗 许一婷 周善康 吴辉煌 

作者机构：厦门大学化学化工学院 

出 版 物：《高等学校化学学报》 (Chemical Journal of Chinese Universities)

年 卷 期：2002年第23卷第6期

页      面：1174-1176页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：国家教育部博士点专项科研基金项目 (批准号 :19990 3 840 4) 中 -法先进研究计划 (PRA-2 0 0 1)资助 

主　　题：膜修饰电极 电化学 催化性质 聚间氯苯胺 金属化聚合物 异丙醇 电催化氧化 化学包修电极 

摘      要：The electrochemical and catalytic properties of PmClAn modified electrode were studied by cyclic voltammetry. The results showed that PmClAn had an excellent electroactivity and proton doping increased the electroactivity. The Pt particles electrodeposited on PmClAn trend towards preferred orientation, and Pt(200) was the preferred face. It was also found that platinized PmClAn promotes isopropanol oxidation, the polymer is not only as a dispersion media of Pt particles forming a microheterogeneous catalysis system, but also has effect on electronic properties of Pt.