Synthesis and Characterization of Novel Schiff Base Macrocyclic Compounds Containing Thiophene
Synthesis and Characterization of Novel Schiff Base Macrocyclic Compounds Containing Thiophene作者机构:Key Laboratory of Synthetic and Natural Functional Molecule Chemistry Ministry of Education College of Chemistry and Materials Science Northwest University Xi' an 710069 P. R. China
出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))
年 卷 期:2014年第30卷第3期
页 面:383-386页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:Supported by the Science Research Project of Shaanxi Provincial Educational Department, China the Science and Technology Plan Project of Xi’an City, China
主 题:Ion recognition Macrocyclic compound Schiff base Thiophene
摘 要:Several novel Schiff base macrocyclic compounds containing thiophene were synthesized from d/ethyl 3,4-dialkoxythiophene-2,5-dicarboxylate, cyanuric chloride, diethylarnine and p-nitrophenol by reduction, oxidation, substitution and cyclization, and their structures were characterized by IR, NMR and electrospray ionization-rnass spectrorneter(ESI-MS). The studies on their UV-Vis absorption spectra show that Schiff base rnacrocycles 6-10 have selective recognition for Fe^3+.