Stereodynamics of O（^3P）＋H2 at Scattering Energies of 0.5, 0.75, and 1.0 eV

作     者：Victor Wei-keh Wu 

作者机构：国立高雄应用科技大学、化学材料工程系高雄80782 胜利者基础研究实验室、比勒费尔德D-33602德国 

出 版 物：《Chinese Journal of Chemical Physics》 (化学物理学报（英文）)

年 卷 期：2010年第23卷第2期

页      面：149-154,I0001页

核心收录：

学科分类：07[理学] 

基　　金：Dalian Institute of Chemical Physics of the Chinese Academy of Sciences Dalian Institute of Chemical Physics of the Chinese Academy of Sciences Victor Basic Research Laboratory e.V. in Bielefeld, Germany 

主　　题：Quasiclassical trajectory calculation Stereodynamics Alignment Rotational angular momentum Polarization dependent differential cross section O+H2 reaction 

摘      要：Quasiclassical trajectory calculation of the title reaction O（^3P）＋H2→OH＋H at three different scattering energies of 0.5, 0.75, and 1.0 eV on the lowest electronic potential energy surface 1^3A＂ has been done. Distribution P（θr） of polar angles between the relative velocityk of the reactant and rotational angular momentum vector j＇ of the product, distribution P（φr） of the azimuthal as well as dihedral angles correlating k-k＇-j＇, 3-dimensional distri-bution, and polarization-dependent differential cross sections （PDDCSs）dependent upon the scattering angle of the product molecule OH between the relative velocity k of the reactant and k＇ of the product at different scattering energies of 0.5, 0.75, and 1.0 eV are presented and discussed.