Enantioselective Pinacol Coupling of Aromatic Aldehydes Mediated by TiCl_4(THF)_2/Zn with Tartaric Ester

作     者：李有桂 江辰 赵俊 田青杉 尤田耙 

作者机构：Department of ChemistryUniversity of Science & Technology of ChinaHefeiAnhui 230026China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2004年第22卷第9期

页      面：950-952页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the National Natural Science Foundation (No. 20172049) of China 

主　　题：pinacol asymmetric coupling enantioselectivity tartaric acid 

摘      要：Asymmetric pinacol coupling of aromatic aldehydes mediated by low valent titanium complexes of chiral ligands derived from natural tartaric acid provided corresponding pinacols in good yields with excellent diastereo-selectivities and moderate enantioselectivities.